Growth, Properties, and Theoretical Analysis of M₂LiVO₄ (M?=?Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials.

ABSTRACT: Mid-Infrared nonlinear optical (Mid-IR NLO) crystals with excellent performances play a particularly important role for applications in areas such as telecommunications, laser guidance, and explosives detection. However, the design and growth of high performance Mid-IR NLO crystals with large NLO efficiency and high laser-damage threshold (LDT) still face numerous fundamental challenge. In this study, two potential Mid-IR NLO materials, Rb₂LiVO₄ (RLVO) and Cs₂LiVO₄ (CLVO) with noncentrosymmetric structures (Orthorhombic, Cmc2₁) were synthesized by high-temperature solution method. Thermal analysis and powder X-ray diffraction demonstrate that RLVO and CLVO melt congruently. Centimeter sized crystals of CLVO have been grown by the top-seeded solution growth method. RLVO and CLVO exhibit strong second harmonic generation (SHG) effects (about 4 and 5 times that of KH₂PO₄, respectively) with a phase-matching behavior at 1.064??m, and a wide transparency range (0.33-6.0??m for CLVO). More importantly, RLVO and CLVO possess a high LDT value (~28?×?AgGaS₂). In addition, the density functional theory (DFT) and dipole moments studies indicate that the VO₄ anionic groups have a dominant contribution to the SHG effects in RLVO and CLVO. These results suggest that the title compounds are promising NLO candidate crystals applied in the Mid-IR region.

SUBMITTER: Han G 

PROVIDER: S-EPMC5432528 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature