Unknown

Dataset Information

0

Catalytic Cracking of Lactide and Poly(Lactic Acid) to Acrylic Acid at Low Temperatures.

ABSTRACT: Despite being a simple dehydration reaction, the industrially relevant conversion of lactic acid to acrylic acid is particularly challenging. For the first time, the catalytic cracking of lactide and poly(lactic acid) to acrylic acid under mild conditions is reported with up to 58 % yield. This transformation is catalyzed by strong acids in the presence of bromide or chloride salts and proceeds through simple SN 2 and elimination reactions.

SUBMITTER: Terrade FG 

PROVIDER: S-EPMC5435937 | biostudies-literature |

REPOSITORIES: biostudies-literature

Json Xml

Similar Datasets

Unknown Lactic Acid Conversion to Acrylic Acid Over Fluoride-Substituted Hydroxyapatites.
| S-EPMC7237761 | biostudies-literature
Unknown Encapsulation of Amikacin into Microparticles Based on Low-Molecular-Weight Poly(lactic acid) and Poly(lactic acid-<i>co</i>-polyethylene glycol).
| S-EPMC8397404 | biostudies-literature
Unknown Evaluation of poly(lactic-co-glycolic acid) and poly(dl-lactide-co-?-caprolactone) electrospun fibers for the treatment of HSV-2 infection.
| S-EPMC5810955 | biostudies-literature
Unknown Alkyl hydroperoxide reductase enhances the growth of Leuconostoc mesenteroides lactic acid bacteria at low temperatures.
| S-EPMC4384994 | biostudies-literature
Unknown Effect of PMMA/Silica Hybrid Particles on Interfacial Adhesion and Crystallization Properties of Poly(lactic acid)/Block Acrylic Elastomer Composites.
| S-EPMC7650821 | biostudies-literature
Unknown Temperature and pH-Dependent Response of Poly(Acrylic Acid) and Poly(Acrylic Acid-co-Methyl Acrylate) in Highly Concentrated Potassium Chloride Aqueous Solutions.
| S-EPMC7077713 | biostudies-literature
Unknown Aggregation of poly(acrylic acid)-containing elastin-mimetic copolymers.
| S-EPMC4376481 | biostudies-literature
Unknown Hemocompatibility of Chitosan/poly(acrylic acid) Grafted Polyurethane Tubing.
| S-EPMC3859438 | biostudies-literature
Unknown Blending with Poly(l-lactic acid) Improves the Printability of Poly(l-lactide-<i>co</i>-caprolactone) and Enhances the Potential Application in Cartilage Tissue Engineering.
| S-EPMC8296602 | biostudies-literature
Unknown Biosourced All-Acrylic ABA Block Copolymers with Lactic Acid-Based Soft Phase.
| S-EPMC7731403 | biostudies-literature