Ontology highlight
ABSTRACT:
SUBMITTER: Kondo H
PROVIDER: S-EPMC5436550 | biostudies-literature | 2017 May
REPOSITORIES: biostudies-literature
Kondo Hiroki H Itami Kenichiro K Yamaguchi Junichiro J
Chemical science 20170315 5
A Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes has been developed. Acyl aminocyclopropanes were reacted with hydrosilanes in the presence of Rh catalysts to afford ring-opened hydrosilylated adducts through carbon-carbon (C-C) bond cleavage of the cyclopropane ring. The regioselectivity of the addition of silanes (linear or branched) can be switched by changing the monophosphine ligand. This C-C bond cleavage/hydrosilylation methodology is applicable to the synthesis of ...[more]