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Accurate Neural Network Description of Surface Phonons in Reactive Gas-Surface Dynamics: N2 + Ru(0001).


ABSTRACT: Ab initio molecular dynamics (AIMD) simulations enable the accurate description of reactive molecule-surface scattering especially if energy transfer involving surface phonons is important. However, presently, the computational expense of AIMD rules out its application to systems where reaction probabilities are smaller than about 1%. Here we show that this problem can be overcome by a high-dimensional neural network fit of the molecule-surface interaction potential, which also incorporates the dependence on phonons by taking into account all degrees of freedom of the surface explicitly. As shown for N2 + Ru(0001), which is a prototypical case for highly activated dissociative chemisorption, the method allows an accurate description of the coupling of molecular and surface atom motion and accurately accounts for vibrational properties of the employed slab model of Ru(0001). The neural network potential allows reaction probabilities as low as 10-5 to be computed, showing good agreement with experimental results.

SUBMITTER: Shakouri K 

PROVIDER: S-EPMC5439174 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Accurate Neural Network Description of Surface Phonons in Reactive Gas-Surface Dynamics: N<sub>2</sub> + Ru(0001).

Shakouri Khosrow K   Behler Jörg J   Meyer Jörg J   Kroes Geert-Jan GJ  

The journal of physical chemistry letters 20170428 10


Ab initio molecular dynamics (AIMD) simulations enable the accurate description of reactive molecule-surface scattering especially if energy transfer involving surface phonons is important. However, presently, the computational expense of AIMD rules out its application to systems where reaction probabilities are smaller than about 1%. Here we show that this problem can be overcome by a high-dimensional neural network fit of the molecule-surface interaction potential, which also incorporates the  ...[more]

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