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CO2 Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System.


ABSTRACT: The cooperative catalytic activity of several metal corrole complexes in combination with tetrabutyl-ammonium bromide (TBAB) has been investigated for the reaction of epoxides with CO2 leading to cyclic carbonates. It was found that the use of just 0.05 mol % of a manganese(III)corrole with 2 mol % TBAB exhibits excellent catalytic activity under an atmosphere of CO2 .

SUBMITTER: Tiffner M 

PROVIDER: S-EPMC5446785 | biostudies-literature |

REPOSITORIES: biostudies-literature

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