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Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2.

ABSTRACT: Identification on catalytic sites of heterogeneous catalysts at atomic level is important to understand catalytic mechanism. Surface engineering on defects of metal oxides can construct new active sites and regulate catalytic activity and selectivity. Here we outline the strategy by controlling surface defects of nanoceria to create the solid frustrated Lewis pair (FLP) metal oxide for efficient hydrogenation of alkenes and alkynes. Porous nanorods of ceria (PN-CeO2) with a high concentration of surface defects construct new Lewis acidic sites by two adjacent surface Ce3+. The neighbouring surface lattice oxygen as Lewis base and constructed Lewis acid create solid FLP site due to the rigid lattice of ceria, which can easily dissociate H-H bond with low activation energy of 0.17?eV.

SUBMITTER: Zhang S

PROVIDER: S-EPMC5454379 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2.

Zhang Sai S Huang Zheng-Qing ZQ Ma Yuanyuan Y Gao Wei W Li Jing J Cao Fangxian F Li Lin L Chang Chun-Ran CR Qu Yongquan Y

Nature communications 20170518

Identification on catalytic sites of heterogeneous catalysts at atomic level is important to understand catalytic mechanism. Surface engineering on defects of metal oxides can construct new active sites and regulate catalytic activity and selectivity. Here we outline the strategy by controlling surface defects of nanoceria to create the solid frustrated Lewis pair (FLP) metal oxide for efficient hydrogenation of alkenes and alkynes. Porous nanorods of ceria (PN-CeO2) with a high conce ...[more]

PMID: 28516952

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