Ontology highlight
ABSTRACT:
SUBMITTER: Lemke HT
PROVIDER: S-EPMC5458100 | biostudies-literature | 2017 May
REPOSITORIES: biostudies-literature
Lemke Henrik T HT Kjær Kasper S KS Hartsock Robert R van Driel Tim B TB Chollet Matthieu M Glownia James M JM Song Sanghoon S Zhu Diling D Pace Elisabetta E Matar Samir F SF Nielsen Martin M MM Benfatto Maurizio M Gaffney Kelly J KJ Collet Eric E Cammarata Marco M
Nature communications 20170524
The description of ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remains challenging because electronic and nuclear configurations impact each other and cannot be treated independently. Here we gain experimental insights, beyond the Born-Oppenheimer approximation, into the light-induced spin-state trapping dynamics of the prototypical [Fe(bpy)<sub>3</sub>]<sup>2+</sup> compound by time-resolved X-ray absorption spectroscopy at sub-30-femtosecond resolution and h ...[more]