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An infinite two-dimensional hybrid water-chloride network in a 4'-(furan-2-yl)-2,2':6',2''-terpyridine nickel(II) matrix.

ABSTRACT: A new complex, namely bis-[4'-(furan-2-yl)-2,2':6',2''-terpyridine]-nickel(II) dichloride deca-hydrate, [Ni(C19H13N3O)2]Cl2·10H2O, has been crystallized by solvent evaporation and characterized by single-crystal X-ray diffraction. The coordination environment of the NiII cation is distorted octa-hedral with slight deviations from an idealized geometry. The most intriguing structural feature is an infinite two-dimensional hybrid water-chloride network parallel to (011) constructed by O-H?O and O-H?Cl hydrogen bonds involving two independent chloride ions and ten independent solvent water mol-ecules with an l-shaped pattern. One of the furyl rings is disordered with a refined occupancy ratio of 0.786?(13):0.214?(13).

SUBMITTER: Fu WW 

PROVIDER: S-EPMC5458313 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature

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An infinite two-dimensional hybrid water-chloride network in a 4'-(furan-2-yl)-2,2':6',2''-terpyridine nickel(II) matrix.

Fu Wei-Wei WW   Li Ya-Qian YQ   Liu Yang Y   Chen Man-Sheng MS   Li Wei W   Yang Ying-Qun YQ  

Acta crystallographica. Section E, Crystallographic communications 20170523 Pt 6

A new complex, namely bis-[4'-(furan-2-yl)-2,2':6',2''-terpyridine]-nickel(II) dichloride deca-hydrate, [Ni(C<sub>19</sub>H<sub>13</sub>N<sub>3</sub>O)<sub>2</sub>]Cl<sub>2</sub>·10H<sub>2</sub>O, has been crystallized by solvent evaporation and characterized by single-crystal X-ray diffraction. The coordination environment of the Ni<sup>II</sup> cation is distorted octa-hedral with slight deviations from an idealized geometry. The most intriguing structural feature is an infinite two-dimensiona  ...[more]

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