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Tris(2-mercaptoimidazolyl)hydroborato Cadmium Thiolate Complexes, [Tm^{Bu^t}]CdSAr: Thiolate Exchange at Cadmium in a Sulfur-Rich Coordination Environment.

ABSTRACT: A series of cadmium thiolate compounds that feature a sulfur-rich coordination environment, namely [Tm^{Bu^t}]CdSAr, have been synthesized by the reactions of [Tm^{Bu^t}]CdMe with ArSH (Ar = C₆H₄-4-F, C₆H₄-4-Bu^t, C₆H₄-4-OMe, and C₆H₄-3-OMe). In addition, the pyridine-2-thiolate and pyridine-2-selenolate derivatives, [Tm^{Bu^t}]CdSPy and [Tm^{Bu^t}]CdSePy have been obtained via the respective reactions of [Tm^{Bu^t}]CdMe with pyridine-2-thione and pyridine-2-selone. The molecular structures of [Tm^{Bu^t}]CdSAr and [Tm^{Bu^t}]CdEPy (E = S or Se) have been determined by X

SUBMITTER: Kreider-Mueller A

PROVIDER: S-EPMC5461919 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature

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Tris(2-mercaptoimidazolyl)hydroborato Cadmium Thiolate Complexes, [Tm^{Bu^t}]CdSAr: Thiolate Exchange at Cadmium in a Sulfur-Rich Coordination Environment.

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Tris(2-mercaptoimidazolyl)hydroborato Cadmium Thiolate Complexes, [TmBut]CdSAr: Thiolate Exchange at Cadmium in a Sulfur-Rich Coordination Environment.

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Tris(2-mercaptoimidazolyl)hydroborato Cadmium Thiolate Complexes, [Tm^{Bu^t}]CdSAr: Thiolate Exchange at Cadmium in a Sulfur-Rich Coordination Environment.