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Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers.


ABSTRACT: Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.

SUBMITTER: Marco AB 

PROVIDER: S-EPMC5485174 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature

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Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers.

Marco A Belen AB   Cortizo-Lacalle Diego D   Perez-Miqueo Iñigo I   Valenti Giovanni G   Boni Alessandro A   Plas Jan J   Strutyński Karol K   De Feyter Steven S   Paolucci Francesco F   Montes Mario M   Khlobystov Andrei N AN   Melle-Franco Manuel M   Mateo-Alonso Aurelio A  

Angewandte Chemie (International ed. in English) 20170320 24


Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media. ...[more]

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