Redox Catalysis Facilitates Lignin Depolymerization.
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ABSTRACT:
SUBMITTER: Bosque I
PROVIDER: S-EPMC5492418 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
Publications
Redox Catalysis Facilitates Lignin Depolymerization.
Bosque Irene I Magallanes Gabriel G Rigoulet Mathilde M Kärkäs Markus D MD Stephenson Corey R J CRJ
ACS central science 20170607 6
Lignin is a recalcitrant and underexploited natural feedstock for aromatic commodity chemicals, and its degradation generally requires the use of high temperatures and harsh reaction conditions. Herein we present an ambient temperature one-pot process for the controlled oxidation and depolymerization of this potent resource. Harnessing the potential of electrocatalytic oxidation in conjugation with our photocatalytic cleavage methodology, we have developed an operationally simple procedure for s ...[more]
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