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Crystal structure of (5-{3-[(1,4,7,10,13-penta-oxa-16-aza-cyclo-octa-decan-16-yl)carbonyl-amino]-phen-yl}-10,15,20-tri-phenyl-porphyrinato)cobalt(II).

ABSTRACT: In the title compound, [Co(C₅₇H₅₂N₆O₆)], the central Co^II atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14?(10) (C_a), 0.20?(10) (C_b), 0.24?(4) (C_m) and 0.18?(10)?Å (C_av), respectively. The axial Co-O bond length is 2.3380?(15) and the average Co-N_p bond length is 1.968?(5)?Å. Intra-molecular N-H?O and inter-molecular C-H?? inter-actions are observed.

SUBMITTER: Wu Q

PROVIDER: S-EPMC5499269 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of (5-{3-[(1,4,7,10,13-penta-oxa-16-aza-cyclo-octa-decan-16-yl)carbonyl-amino]-phen-yl}-10,15,20-tri-phenyl-porphyrinato)cobalt(II).

Wu Qi Q He Mingrui M Li Jianfeng J

Acta crystallographica. Section E, Crystallographic communications 20170607 Pt 7

In the title compound, [Co(C57H52N6O6)], the central CoII atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (Ca), 0.20 (10) (Cb), 0.24 (4) (Cm) and 0.18 (10) Å (Cav), respectively. The axial Co-O bond length is 2.3380 (15) ...[more]

PMID: 28775861

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