Ontology highlight
ABSTRACT:
SUBMITTER: Wu Q
PROVIDER: S-EPMC5499269 | biostudies-literature | 2017 Jul
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20170607 Pt 7
In the title compound, [Co(C<sub>57</sub>H<sub>52</sub>N<sub>6</sub>O<sub>6</sub>)], the central Co<sup>II</sup> atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (<i>C</i><sub>a</sub>), 0.20 (10) (<i>C</i><sub>b</sub>), 0.24 (4) (<i>C</i><sub>m</sub>) and 0.18 (10) Å (<i>C</i><sub>av</sub>), respectively. The axial Co-O bond length is 2.3380 (15) ...[more]