Ontology highlight
ABSTRACT:
SUBMITTER: Sanna E
PROVIDER: S-EPMC5505123 | biostudies-literature | 2015 Oct
REPOSITORIES: biostudies-literature
Sanna Elena E Escudero-Adán Eduardo C EC Bauzá Antonio A Ballester Pablo P Frontera Antonio A Rotger Carmen C Costa Antonio A
Chemical science 20150714 10
A crystalline porous material showing one-dimensional (1-D) rectangular micropores (12 × 9 Å<sup>2</sup>) has been assembled from a semirigid macrocyclic tetraimine and EtOAc as the templating agent. The 1-D nature of the material is intrinsic to the conformationally rigid structure of a macrocyclic sub-unit bearing four cyclohexylidene residues. The multiple dispersive forces established among the aliphatic residues glutted the 1-D channels and provided thermal stability to the material at temp ...[more]