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ABSTRACT:
SUBMITTER: Ge X
PROVIDER: S-EPMC5507371 | biostudies-literature | 2015 Apr
REPOSITORIES: biostudies-literature
Macromolecular chemistry and physics 20150211 8
The effects of polymerization kinetics and chemical miscibility on the crosslinking structure and mechanical properties of polymers cured by visible-light initiated free-radical/cationic ring-opening hybrid photopolymerization are determined. A three-component initiator system is used and the monomer system contains methacrylates and epoxides. The photopolymerization kinetics is monitored in situ by Fourier transform infrared-attenuated total reflectance. The crosslinking structure is studied by ...[more]