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Naphthalenebisimides as photofunctional surfactants for SWCNTs - towards water-soluble electron donor-acceptor hybrids.

ABSTRACT: A water soluble naphthalenebisimide derivative (NBI) was synthesized and probed to individualize, suspend, and stabilize single wall carbon nanotubes (SWCNTs). Besides a comprehensive photophysical and electrochemical characterization of NBI, stable suspensions of SWCNTs were realized in buffered D₂O. Overall, the dispersion efficiency of the NBI surfactant was determined by comparison with naphthalene based references. Successful individualization of SWCNTs was corroborated in several microscopic assays. In addition, emission spectroscopy points to the strong quenching of SWCNT centered band gap emission, when NBIs are immobilized onto SWCNTs. The origin of the quenching was found to be strong electronic communication, which leads to charge separation between NBIs and photoexcited SWCNTs, and, which yields reduced NBIs as well oxidized SWCNTs. Notably, electrochemical considerations revealed that the energy content of these charge separated states is one of the highest reported for SWCNT based electron donor-acceptor hybrids so far.

SUBMITTER: Dirian K

PROVIDER: S-EPMC5510015 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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Naphthalenebisimides as photofunctional surfactants for SWCNTs - towards water-soluble electron donor-acceptor hybrids.

Dirian Konstantin K Backes Susanne S Backes Claudia C Strauss Volker V Rodler Fabian F Hauke Frank F Hirsch Andreas A Guldi Dirk M DM

Chemical science 20150922 12

A water soluble naphthalenebisimide derivative (NBI) was synthesized and probed to individualize, suspend, and stabilize single wall carbon nanotubes (SWCNTs). Besides a comprehensive photophysical and electrochemical characterization of NBI, stable suspensions of SWCNTs were realized in buffered D<sub>2</sub>O. Overall, the dispersion efficiency of the NBI surfactant was determined by comparison with naphthalene based references. Successful individualization of SWCNTs was corroborated in severa ...[more]

PMID: 28757977

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Naphthalenebisimides as photofunctional surfactants for SWCNTs - towards water-soluble electron donor-acceptor hybrids.

Publications

Naphthalenebisimides as photofunctional surfactants for SWCNTs - towards water-soluble electron donor-acceptor hybrids.

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