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Controllable Layered Structures in Polyoxomolybdate-Surfactant Hybrid Crystals


ABSTRACT: Inorganic-organic hybrid crystals containing ?-octamolybdate (Mo8) or hexamolybdate (Mo6) were isolated by using hexadecyltrimethylammonium (C16) surfactant. The packing mode of the inorganic layers depended on a difference in the polyoxomolybdate molecular structure. The structure for both crystals consisted of alternate stacking of C16 organic bilayers and polyoxomolybdate inorganic layers with a periodicity of 24.4–24.6 Å. However, the C16-Mo8 crystals contained Mo8 monolayers, while the C16-Mo6 crystals contained Mo6 bilayers. These lattice structures for the polyoxometalate/organic hybrid will be designed by the molecular structures of polyoxometalate.

SUBMITTER: Ito T 

PROVIDER: S-EPMC5510187 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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