Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

A Facile Process for the Preparation of Three-Dimensional Hollow Zn(OH)2 Nanoflowers at Room Temperature.

ABSTRACT: A facile strategy has been developed to synthesize double-shelled Zn(OH)2 nanoflowers (DNFs) at room temperature. The nanoflowers were generated via conversion of Cu2 O nanoparticles (NPs) using ZnCl2 and Na2 S2 O3 by a simple process. Outward diffusion of the Cu(2+) , produced by an oxidation process on the surface of NPs, and the inward diffusion of Zn(2+) by coordination and migration, eventually lead to a hollow cavity in the inner NPs with a double-shelled 3D hollow flower shapes. The thickness of the inner and outer shells is estimated to be about 20?nm, and the thickness of nanopetals is about 7?nm. The nanoflowers have large surface areas and excellent adsorption properties. As a proof of potential applications, the DNFs exhibited an excellent ability to remove organic molecules from aqueous solutions.

SUBMITTER: Cai R

PROVIDER: S-EPMC5512704 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

A Facile Process for the Preparation of Three-Dimensional Hollow Zn(OH)2 Nanoflowers at Room Temperature.

Cai Ren R Yang Dan D Zhang Liqing L Qiu Liping L Liang Hao H Chen Xigao X Cansiz Sena S Zhang Zuxiao Z Wan Shuo S Stewart Kimberly K Yan Qingyu Q Tan Weihong W

Chemistry (Weinheim an der Bergstrasse, Germany) 20160704 32

A facile strategy has been developed to synthesize double-shelled Zn(OH)2 nanoflowers (DNFs) at room temperature. The nanoflowers were generated via conversion of Cu2 O nanoparticles (NPs) using ZnCl2 and Na2 S2 O3 by a simple process. Outward diffusion of the Cu(2+) , produced by an oxidation process on the surface of NPs, and the inward diffusion of Zn(2+) by coordination and migration, eventually lead to a hollow cavity in the inner NPs with a double-shelled 3D hollow flower shapes. The thick ...[more]

PMID: 27246606

Similar Datasets

Facile Preparation of Chloride-Conducting Membranes: First Step towards a Room-Temperature Solid-State Chloride-Ion Battery.

Project description:Three types of chloride-conducting membranes based on polyvinyl chloride, commercial gelatin, and polyvinyldifluoride-hexafluoropolymer are introduced in this report. The polymers are mixed with chloride-containing salts, such as tetrabutylammonium chloride, and cast to form membranes. We studied the structural properties, thermal stability, and electrochemical response of the membranes to understand chloride migration and transport. Finally, the membranes are tested in a prototype solid-state chloride-ion battery setup. The feasibility of the membranes for their potential use in anion batteries is discussed.

| S-EPMC5167400 | biostudies-other

Preparation and Properties of Organic-Inorganic Hybrid Antireflection Films Made by a Low-Temperature Process Using Hollow Silica Nanoparticles.

Project description:Layers made of hollow silica nanoparticles have potential applications as antireflection films with lower refractive index values compared with existing materials such as silica glass (1.50) and magnesium fluoride (1.38). The advantages of such nanoparticles result from interactions between the solid shell, the cavity phase core, and the voids between particles. To obtain practical antireflection films, it is necessary to control the number of layers of these hollow silica nanoparticles and to fill the gaps between particles with a solid. In the present study, antireflection films were prepared by applying a coating of hollow silica nanoparticles dispersed in a UV-curable monomer solution onto plastic substrates. After film formation and exposure to UV light, the voids between the nanoparticles were completely filled with a polymer matrix. Tuning the particle concentration in the coating solution allowed the formation of antireflection films comprising one to three layers of the hollow silica nanoparticles. The reflectance of the films was dependent on the number of layers, and a 100 nm thick film in which two layers of hollow silica nanoparticles were precisely arranged showed the lowest reflectance of 0.92% at 550 nm wavelength, equivalent to a refractive index of 1.23. Because the voids between particles were filled with the polymer, these films resisted contamination during manual handling and so would be expected to maintain low reflectance during practical applications. This work demonstrates that nanosized inorganic-organic hybrid films composed of hollow silica nanoparticles and a UV-curable resin can exhibit optical properties and structural integrity that cannot be achieved by either substance alone.

| S-EPMC8015096 | biostudies-literature

Room-temperature exciton-polaritons with two-dimensional WS2.

Project description:Two-dimensional transition metal dichalcogenides exhibit strong optical transitions with significant potential for optoelectronic devices. In particular they are suited for cavity quantum electrodynamics in which strong coupling leads to polariton formation as a root to realisation of inversionless lasing, polariton condensation and superfluidity. Demonstrations of such strongly correlated phenomena to date have often relied on cryogenic temperatures, high excitation densities and were frequently impaired by strong material disorder. At room-temperature, experiments approaching the strong coupling regime with transition metal dichalcogenides have been reported, but well resolved exciton-polaritons have yet to be achieved. Here we report a study of monolayer WS2 coupled to an open Fabry-Perot cavity at room-temperature, in which polariton eigenstates are unambiguously displayed. In-situ tunability of the cavity length results in a maximal Rabi splitting of ??Rabi?=?70?meV, exceeding the exciton linewidth. Our data are well described by a transfer matrix model appropriate for the large linewidth regime. This work provides a platform towards observing strongly correlated polariton phenomena in compact photonic devices for ambient temperature applications.

| S-EPMC5027543 | biostudies-literature

Artificial two-dimensional polar metal at room temperature.

Project description:Polar metals, commonly defined by the coexistence of polar crystal structure and metallicity, are thought to be scarce because the long-range electrostatic fields favoring the polar structure are expected to be fully screened by the conduction electrons of a metal. Moreover, reducing from three to two dimensions, it remains an open question whether a polar metal can exist. Here we report on the realization of a room temperature two-dimensional polar metal of the B-site type in tri-color (tri-layer) superlattices BaTiO3/SrTiO3/LaTiO3. A combination of atomic resolution scanning transmission electron microscopy with electron energy-loss spectroscopy, optical second harmonic generation, electrical transport, and first-principles calculations have revealed the microscopic mechanisms of periodic electric polarization, charge distribution, and orbital symmetry. Our results provide a route to creating all-oxide artificial non-centrosymmetric quasi-two-dimensional metals with exotic quantum states including coexisting ferroelectric, ferromagnetic, and superconducting phases.

| S-EPMC5906683 | biostudies-literature

Facile room temperature synthesis of large graphene sheets from simple molecules.

Project description:The largest graphene sample obtained through a chemical reaction under ambient conditions (temperature and pressure), using simple molecules such as benzene or n-hexane as precursors, is reported. Starting from a heterogeneous reaction between solid iron chloride and the molecular precursor (benzene and n-hexane) at a water/oil interface, graphene sheets with micrometric lateral size are obtained as a film deposited at the liquid/liquid (L/L) interface. The pathway involving the cyclization and aromatization of n-hexane to benzene at the L/L interface, and the sequence of conversion of benzene to biphenyl and biphenyl to condensed rings (which originates the graphene structures) was followed by different characterization techniques and a mechanistic proposal is presented. Finally, we demonstrate that this route can be extended for the synthesis of N-doped graphene, using pyridine as the molecular precursor.

| S-EPMC6167947 | biostudies-literature

Facile Room-Temperature Preparation of Flexible Polyurethane Foams from Carbon Dioxide Based Poly(ether carbonate) Polyols with a Reduced Generation of Acetaldehyde.

Project description:Carbon dioxide (CO2) is becoming more attractive as a renewable feedstock for chemical synthesis. In this study, CO2 was incorporated into poly(ether carbonate) (PEC) polyols by using a double-metal-cyanide catalyst. By adjusting the CO2 pressure, the content of propylene carbonate units in the PEC polyols was controlled, indicating successful and semiquantitative incorporation of CO2 into the PEC polyols. Polyurethane foams (PUFs) with different propylene carbonate content were easily prepared at room temperature by employing the PEC polyols due to their adequate viscosity under ambient conditions. The firmness of the PUFs increased as the amount of propylene carbonate units increased due to the rigidity of the carbonate linkage, representing predictable mechanical properties. Interestingly, reduced generation of volatile organic compounds (VOCs) from the PUFs, namely acetaldehyde, was observed with a high content of propylene carbonate units at 120 °C, indicating good stability of the carbonate units against thermo-oxidative decomposition. This study demonstrates the importance of CO2 as an environmental-friendly and renewable resource that can provide not only industrially important but also problem-solving products in terms of processability and low generation of VOCs.

| S-EPMC6648153 | biostudies-literature

Developing Hollow-Channel Gold Nanoflowers as Trimodal Intracellular Nanoprobes.

Project description:Gold nanoparticles-enabled intracellular surface-enhanced Raman spectroscopy (SERS) provides a sensitive and promising technique for single cell analysis. Compared with spherical gold nanoparticles, gold nanoflowers, i.e., flower-shaped gold nanostructures, can produce a stronger SERS signal. Current exploration of gold nanoflowers for intracellular SERS has been considerably limited by the difficulties in preparation, as well as background signal and cytotoxicity arising from the surfactant capping layer. Recently, we have developed a facile and surfactant-free method for fabricating hollow-channel gold nanoflowers (HAuNFs) with great single-particle SERS activity. In this paper, we investigate the cellular uptake and cytotoxicity of our HAuNFs using a RAW 264.7 macrophage cell line, and have observed effective cellular internalization and low cytotoxicity. We have further engineered our HAuNFs into SERS-active tags, and demonstrated the functionality of the obtained tags as trimodal nanoprobes for dark-field and fluorescence microscopy imaging, together with intracellular SERS.

| S-EPMC6121537 | biostudies-literature

Preparation of biopolymer fibers by electrospinning from room temperature ionic liquids.

Project description:Electrospinning is a versatile process used to prepare micro- and nano- sized fibers from various polymers dissolved in volatile solvents. In this report, cellulose and cellulose-heparin composite fibers are prepared from nonvolatile room temperature ionic liquid (RTIL) solvents by electrospinning. RTILs are extracted from the biopolymer fiber after the fiber formation using a cosolvent. Micron to nanometer sized, branched fibers were obtained from 10% (w/w) concentration of polysaccharide biopolymer in RTIL solution with an applied voltage of 15-20 kV. Cellulose-heparin composite fibers showed anticoagulant activity, demonstrating that the bioactivity of heparin remained unaffected even on exposure to a high voltage involved in electrospinning.

| S-EPMC4777308 | biostudies-literature

Photothermal therapy of cancer cells using novel hollow gold nanoflowers.

Project description:This article presents a new strategy for fabricating large gold nanoflowers (AuNFs) that exhibit high biological safety under visible light and very strong photothermal cytotoxicity to HeLa cells under irradiation with near-infrared (NIR) light. This particular type of AuNF was constructed using vesicles produced from a multiamine head surfactant as a template followed by depositing gold nanoparticles (AuNPs) and growing their crystallites on the surface of vesicles. The localized surface plasmon-resonance spectrum of this type of AuNF can be easily modulated to the NIR region by controlling the size of the AuNFs. When the size of the AuNFs increased, biosafety under visible light improved and cytotoxicity increased under NIR irradiation. Experiments in vitro with HeLa cells and in vivo with small mice have been carried out, with promising results. The mechanism for this phenomenon is based on the hypothesis that it is difficult for larger AuNFs to enter the cell without NIR irradiation, but they enter the cell easily at the higher temperatures caused by NIR irradiation. We believe that these effects will exist in other types of noble metallic NPs and cancer cells. In addition, the affinity between AuNPs and functional biomolecules, such as aptamers and biomarkers, will make this type of AuNF a good recognition device in cancer diagnosis and therapy.

| S-EPMC3897319 | biostudies-literature

Effects of Lipid Tethering in Extremophile-Inspired Membranes on H(+)/OH(-) Flux at Room Temperature.

Project description:This work explores the proton/hydroxide permeability (PH+/OH-) of membranes that were made of synthetic extremophile-inspired phospholipids with systematically varied structural elements. A fluorescence-based permeability assay was optimized to determine the effects on the PH+/OH- through liposome membranes with variations in the following lipid attributes: transmembrane tethering, tether length, and the presence of isoprenoid methyl groups on one or both lipid tails. All permeability assays were performed in the presence of a low concentration of valinomycin (10 nM) to prevent buildup of a membrane potential without artificially increasing the measured PH+/OH-. Surprisingly, the presence of a transmembrane tether did not impact PH+/OH- at room temperature. Among tethered lipid monolayers, PH+/OH- increased with increasing tether length if the number of carbons in the untethered acyl tail was constant. Untethered lipids with two isoprenoid methyl tails led to lower PH+/OH- values than lipids with only one or no isoprenoid tails. Molecular dynamics simulations revealed a strong positive correlation between the probability of observing water molecules in the hydrophobic core of these lipid membranes and their proton permeability. We propose that water penetration as revealed by molecular dynamics may provide a general strategy for predicting proton permeability through various lipid membranes without the need for experimentation.

| S-EPMC4906265 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data