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Synthesis of 1,3-Substituted Cyclobutanes by Allenoate-Alkene [2 + 2] Cycloaddition.


ABSTRACT: A method for the [2 + 2] cycloaddition of terminal alkenes with allenoates is presented. This process allows for the rapid synthesis of 1,3-substituted cyclobutanes in high yield under simple and robust reaction conditions.

SUBMITTER: Conner ML 

PROVIDER: S-EPMC5534137 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature

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Synthesis of 1,3-Substituted Cyclobutanes by Allenoate-Alkene [2 + 2] Cycloaddition.

Conner Michael L ML   Brown M Kevin MK  

The Journal of organic chemistry 20160825 17


A method for the [2 + 2] cycloaddition of terminal alkenes with allenoates is presented. This process allows for the rapid synthesis of 1,3-substituted cyclobutanes in high yield under simple and robust reaction conditions. ...[more]

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