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Geostatistical exploration of dataset assessing the heavy metal contamination in Ewekoro limestone, Southwestern Nigeria.

ABSTRACT: The dataset for this article contains geostatistical analysis of heavy metals contamination from limestone samples collected from Ewekoro Formation in the eastern Dahomey basin, Ogun State Nigeria. The samples were manually collected and analysed using Microwave Plasma Atomic Absorption Spectrometer (MPAS). Analysis of the twenty different samples showed different levels of heavy metals concentration. The analysed nine elements are Arsenic, Mercury, Cadmium, Cobalt, Chromium, Nickel, Lead, Vanadium and Zinc. Descriptive statistics was used to explore the heavy metal concentrations individually. Pearson, Kendall tau and Spearman rho correlation coefficients was used to establish the relationships among the elements and the analysis of variance showed that there is a significant difference in the mean distribution of the heavy metals concentration within and between the groups of the 20 samples analysed. The dataset can provide insights into the health implications of the contaminants especially when the mean concentration levels of the heavy metals are compared with recommended regulatory limit concentration.

SUBMITTER: Oyeyemi KD

PROVIDER: S-EPMC5537382 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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Geostatistical exploration of dataset assessing the heavy metal contamination in Ewekoro limestone, Southwestern Nigeria.

Oyeyemi Kehinde D KD Aizebeokhai Ahzegbobor P AP Aizebeokhai Ahzegbobor P AP Okagbue Hilary I HI

Data in brief 20170721

The dataset for this article contains geostatistical analysis of heavy metals contamination from limestone samples collected from Ewekoro Formation in the eastern Dahomey basin, Ogun State Nigeria. The samples were manually collected and analysed using Microwave Plasma Atomic Absorption Spectrometer (MPAS). Analysis of the twenty different samples showed different levels of heavy metals concentration. The analysed nine elements are Arsenic, Mercury, Cadmium, Cobalt, Chromium, Nickel, Lead, Vanad ...[more]

PMID: 28795088

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Project description:BackgroundIncreased growth of industrial activities, especially in urban centers, is one of the main sources of toxic substances in Nigeria. The level of these impacts is not well known. Soil and sediment samples from one such industrial area were examined for their mineralogical composition and heavy metals contents in order to assess the level of contamination and potential ecological risk status.MethodsMineralogical composition of the media and their heavy metals concentrations were determined using X-ray diffractometry and inductively coupled plasma-mass spectrometry methods, respectively. Ecological risk assessment was carried out using single (contamination factor, geo-accumulation index, enrichment factor) and multi-elemental (contamination degree, pollution index and modified pollution index) standard indices.ResultsThe average heavy metal concentrations in soils and sediments followed the order magnesium (Mn) > chromium (Cr) > lead (Pb) > copper (Cu) > cadmium (Cd) > cobalt (Co) > nickel (Ni), with corresponding values for soils and sediments of 324.3, 79.9, 66.1, 40.7, 14.3, 9.1, 6.8 mg kg-1 and 266.8, 78.6, 40.6, 39.8, 12.9, 8.4, 4.6 mg kg-1, respectively. Principal component (PC) analysis of the results indicated three main sources of metals (industrial, vehicular activities and geogenic input). Evaluated contamination factor (Cf), enrichment factor (Ef) and geo-accumulation index (Igeo) revealed very high contamination for Pb, Cd and Cu in all of the samples, with calculated pollution index (PI) and modified pollution index (MPI) revealing that all the samples were severely polluted. Calculated potential ecological risk factor (ERi) within the industrial area demonstrated a strong potential ecological risk for Cd, Pb and Cu.ConclusionsActivities in the industrial area have affected the quality of the analyzed environmental media, with possible detrimental health consequences. Regular environmental monitoring of the industrial area and the formulation of appropriate policies that support reduction of contamination are strongly recommended. However, due to the limitations of comparing site samples with a single control sample in this work, further study is recommended to compliment this preliminary study.Competing interestsThe authors declare no competing financial interests.

Project description:BackgroundGroundwater quality can be poor in Nigeria due to indiscriminate refuse dumping. Exposed dumps serve as point source pollution that discharge potentially toxic heavy metals into the environment.ObjectivesThe present research aimed to assess the impact of metal pollution on groundwater quality in hand-dug wells around an active dumpsite and to evaluate the long-term human health effects of this pollution.MethodsWater samples from hand-dug wells used for drinking, irrigation and domestic purposes were collected around the dumpsite. Two samples were collected at each location for cation and anion analyses. Samples for cation analysis were acidified with concentrated hydrochloric acid to preserve the elements in the samples, while those for anion analysis were not acidified. Collected samples were analyzed using inductively coupled plasma mass spectrometry and atomic absorption spectroscopy.ResultsMean concentrations of metals and physical parameters were compared with the World Health Organization's standards (2012). All samples were found to be within permissible limits, except for arsenic (As) (0.13 mg/L), potassium (K) (29.94 mg/L), lead (Pb) (0.38 mg/L), cadmium (Cd) (0.003 mg/L) and average temperature (31.93°C) as a result of corroded service pipes containing Pb in the dumpsites and the reaction of leachates with various materials such as used battery, tins, and electronic wastes which later leaked into the groundwater. The geoaccumulation index revealed Pb to be moderately to highly contaminated in groundwater.ConclusionsHeavy metal pollution can cause deleterious health effects that can lead to short- and long-term diseases such as keratosis (skin hardening), lung cancer, bladder cancer and ultimately death if proactive steps are not taken. Disposal bags should be provided to all houses in the area, as well as guaranteed waste disposal trucks and dispose of waste at approved sites. In addition, enforcement agents should ensure compliance with rules and regulations. A centralized, deep, double-cased well should be constructed in a clean environment in the study area for drinking and domestic use.Competing interestsThe authors declare no competing financial interests.

Dataset Information

Geostatistical exploration of dataset assessing the heavy metal contamination in Ewekoro limestone, Southwestern Nigeria.

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Geostatistical exploration of dataset assessing the heavy metal contamination in Ewekoro limestone, Southwestern Nigeria.

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