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Silica Mineralization of DNA-Inspired 1D and 2D Supramolecular Polymers.


ABSTRACT: The preparation of hybrid materials from supramolecular polymers through the sol-gel process is presented. Supramolecular polymers are assembled from phosphodiester-linked pyrene oligomers and act as water-soluble one- or two-dimensional templates for silicification. The fibrillary and planar morphologies of the assemblies, as well as the excitonic interactions between the chromophores, remain unaffected by the silicification process.

SUBMITTER: Vybornyi M 

PROVIDER: S-EPMC5542747 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature

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Silica Mineralization of DNA-Inspired 1D and 2D Supramolecular Polymers.

Vybornyi Mykhailo M   Vyborna Yuliia Y   Häner Robert R  

ChemistryOpen 20170623 4


The preparation of hybrid materials from supramolecular polymers through the sol-gel process is presented. Supramolecular polymers are assembled from phosphodiester-linked pyrene oligomers and act as water-soluble one- or two-dimensional templates for silicification. The fibrillary and planar morphologies of the assemblies, as well as the excitonic interactions between the chromophores, remain unaffected by the silicification process. ...[more]

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