Ontology highlight
ABSTRACT:
SUBMITTER: Naghavi SS
PROVIDER: S-EPMC5561097 | biostudies-literature | 2017 Aug
REPOSITORIES: biostudies-literature
Naghavi S Shahab SS Emery Antoine A AA Hansen Heine A HA Zhou Fei F Ozolins Vidvuds V Wolverton Chris C
Nature communications 20170818 1
Previous studies have shown that a large solid-state entropy of reduction increases the thermodynamic efficiency of metal oxides, such as ceria, for two-step thermochemical water splitting cycles. In this context, the configurational entropy arising from oxygen off-stoichiometry in the oxide, has been the focus of most previous work. Here we report a different source of entropy, the onsite electronic configurational entropy, arising from coupling between orbital and spin angular momenta in lanth ...[more]