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An Alternative Host Material for Long-Lifespan Blue Organic Light-Emitting Diodes Using Thermally Activated Delayed Fluorescence.


ABSTRACT: It has been challenging to find stable blue organic light emitting diodes (OLEDs) that rely on thermally activated delayed fluorescence (TADF). Lack of stable host materials well-fitted to the TADF emitters is one of the critical reasons. The most popular host for blue TADF, bis[2-(diphenylphosphino)phenyl] ether oxide (DPEPO), leads to unrealistically high maximum external quantum efficiency. DPEPO is however an unstable material and has a poor charge transporting ability, which in turn induces an intrinsic short OLED operating lifespan. Here, an alternative host material is introduced which educes the potential efficiency and device lifespan of given TADF emitters with the appropriateness of replacing the most popular host material, DPEPO, in developing blue TADF emitters. It simultaneously provides much longer device lifespan and higher external quantum efficiency at a practical brightness due to its high material stability and electron-transport-type character well-fitted for hole-transport-type TADF emitters.

SUBMITTER: Ihn SG 

PROVIDER: S-EPMC5566347 | biostudies-literature | 2017 Aug

REPOSITORIES: biostudies-literature

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An Alternative Host Material for Long-Lifespan Blue Organic Light-Emitting Diodes Using Thermally Activated Delayed Fluorescence.

Ihn Soo-Ghang SG   Lee Namheon N   Jeon Soon Ok SO   Sim Myungsun M   Kang Hosuk H   Jung Yongsik Y   Huh Dal Ho DH   Son Young Mok YM   Lee Sae Youn SY   Numata Masaki M   Miyazaki Hiroshi H   Gómez-Bombarelli Rafael R   Aguilera-Iparraguirre Jorge J   Hirzel Timothy T   Aspuru-Guzik Alán A   Kim Sunghan S   Lee Sangyoon S  

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20170323 8


It has been challenging to find stable blue organic light emitting diodes (OLEDs) that rely on thermally activated delayed fluorescence (TADF). Lack of stable host materials well-fitted to the TADF emitters is one of the critical reasons. The most popular host for blue TADF, bis[2-(diphenylphosphino)phenyl] ether oxide (DPEPO), leads to unrealistically high maximum external quantum efficiency. DPEPO is however an unstable material and has a poor charge transporting ability, which in turn induces  ...[more]

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