Ontology highlight
ABSTRACT:
SUBMITTER: Stafford H
PROVIDER: S-EPMC5575506 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20170526 26
The reaction of [Zr(Tren<sup>DMBS</sup> )(Cl)] [Zr1; Tren<sup>DMBS</sup> =N(CH<sub>2</sub> CH<sub>2</sub> NSiMe<sub>2</sub> Bu<sup>t</sup> )<sub>3</sub> ] with NaPH<sub>2</sub> gave the terminal parent phosphanide complex [Zr(Tren<sup>DMBS</sup> )(PH<sub>2</sub> )] [Zr2; Zr-P=2.690(2) Å]. Treatment of Zr2 with one equivalent of KCH<sub>2</sub> C<sub>6</sub> H<sub>5</sub> and two equivalents of benzo-15-crown-5 ether (B15C5) afforded an unprecedented example (outside of matrix isolation) of a str ...[more]