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Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts.

ABSTRACT: The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3] n [TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4] n [FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

SUBMITTER: Elsayed Moussa M 

PROVIDER: S-EPMC5586200 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

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Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp<sub>2</sub>Mo<sub>2</sub>(CO)<sub>4</sub>(η<sup>2</sup>-P<sub>2</sub>)] Complex and Silver(I) Salts.

Elsayed Moussa Mehdi M   Fleischmann Martin M   Peresypkina Eugenia V EV   Dütsch Luis L   Seidl Michael M   Balázs Gabor G   Scheer Manfred M  

European journal of inorganic chemistry 20170706 25

The reactions of the tetrahedral diphosphorus [Cp<sub>2</sub>Mo<sub>2</sub>(CO)<sub>4</sub>(η<sup>2</sup>-P<sub>2</sub>)] (<b>1</b>; Cp = C<sub>5</sub>H<sub>5</sub>) complex with Ag[Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>] (AgTEF) (<b>A</b>) and Ag[FAl{OC(C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>10</sub>)}<sub>3</sub>] (AgFAl) (<b>B</b>) were studied. The first reaction led to the formation of the [Ag<sub>2</sub>(η<sup>2</sup>-<b>1</b>)<sub>2</sub>(η<sup>1</sup>:η<sup>1</sup>-<b>1</  ...[more]

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