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Ruthenium-Catalyzed Amination of Secondary Alcohols using Borrowing Hydrogen Methodology.

ABSTRACT: A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols and diamines lead to heterocyclic ring systems.

SUBMITTER: Marichev KO

PROVIDER: S-EPMC5604847 | biostudies-literature | 2016 Apr

REPOSITORIES: biostudies-literature

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Ruthenium-Catalyzed Amination of Secondary Alcohols using Borrowing Hydrogen Methodology.

Marichev Kostiantyn O KO Takacs James M JM

ACS catalysis 20160223 4

A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols and diamines lead to heterocyclic ring systems. ...[more]

PMID: 28936364

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