Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Photonic Shape Memory Polymer with Stable Multiple Colors.

ABSTRACT: A photonic shape memory polymer film that shows large color response (?155 nm) in a wide temperature range has been fabricated from a semi-interpenetrating network of a cholesteric polymer and poly(benzyl acrylate). The large color response is achieved by mechanical embossing of the photonic film above its broad glass transition temperature. The embossed film, as it recovers to its original shape on heating through the broad thermal transition, exhibits multiple structural colors ranging from blue to orange. The relaxation behavior of the embossed film can be fully described using a Kelvin-Voigt model, which reveals that the influence of temperature on the generation of colors is much stronger than that of time, thereby producing stable multiple colors.

SUBMITTER: Moirangthem M

PROVIDER: S-EPMC5609120 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Photonic Shape Memory Polymer with Stable Multiple Colors.

Moirangthem Monali M Engels Tom A P TAP Murphy Jeffrey J Bastiaansen Cees W M CWM Schenning Albertus P H J APHJ

ACS applied materials & interfaces 20170905 37

A photonic shape memory polymer film that shows large color response (∼155 nm) in a wide temperature range has been fabricated from a semi-interpenetrating network of a cholesteric polymer and poly(benzyl acrylate). The large color response is achieved by mechanical embossing of the photonic film above its broad glass transition temperature. The embossed film, as it recovers to its original shape on heating through the broad thermal transition, exhibits multiple structural colors ranging from bl ...[more]

PMID: 28840717

Similar Datasets

Shape Memory Cellulose-Based Photonic Reflectors.

Project description:Biopolymer-based composites enable to combine different functionalities using renewable materials and cost-effective routes. Here we fabricate novel thermoresponsive photonic films combining cellulose nanocrystals (CNCs) with a polydiolcitrate elastomer exhibiting shape memory properties, known as hydroxyl-dominant poly(dodecanediol-co-citrate) (PDDC-HD). Iridescent films of CNCs are first made by evaporation-induced self-assembly, then embedded in the PDDC-HD prepolymer, and finally cured to obtain a cross-linked composite with shape memory properties. The fabricated samples are characterized by polarized optical microscopy, scanning electron microscopy, and thermomechanical cycling. The obtained hybrid material combines both intense structural coloration and shape memory effect. The association of stiff cellulose nanocrystals and soft polydiolcitrate elastomer enhances the overall mechanical properties (increased modulus and reduced brittleness). This hybrid nanocomposite takes advantage of two promising materials and expands their possibilities to cover a wide range of potential applications as multiresponsive devices and sensors. As they perform from room to body temperatures, they could be also good candidates for biomedical applications.

| S-EPMC5495156 | biostudies-literature

Amorphous Photonic Structures with Brilliant and Noniridescent Colors via Polymer-Assisted Colloidal Assembly.

Project description:Efficient and large area fabrication of amorphous photonic crystals (APCs) with multicolor, angle independency, and fine resolution is always desired owing to their application in color displays, sensors, and pigments. Here, we report a polymer-assisted colloidal assembly (PACA) method to fabricate APCs with brilliant structural colors by the co-assembly of silica colloidal particles, polyvinylpyrrolidone (PVP), and carbon black (CB). PVP is the key to enable the amorphous aggregations of the particles, the uniform and noniridescent structural colors of the APCs. Moreover, multicolor and high-resolution patterns can be prepared through the mask-based brush printing with colloids-PVP-CB precursor solution as ink (named as APCs-ink). The developed printing method can be applied to various substrates with different roughness, curvature, and flexibility such as papers, metals, plastic films, stones, and even curved glasses. PACA is efficient and straightforward for the fabrication of APCs and high-resolution patterns with large area, low cost, and easy operation, which will facilitate their practical applications in the fields of color-related display, green painting, anticounterfeiting, and so on.

| S-EPMC6854835 | biostudies-literature

Reconfigurable photonic crystals enabled by pressure-responsive shape-memory polymers.

Project description:Smart shape-memory polymers can memorize and recover their permanent shape in response to an external stimulus (for example, heat). They have been extensively exploited for a wide spectrum of applications ranging from biomedical devices to aerospace morphing structures. However, most of the existing shape-memory polymers are thermoresponsive and their performance is hindered by heat-demanding programming and recovery steps. Although pressure is an easily adjustable process variable such as temperature, pressure-responsive shape-memory polymers are largely unexplored. Here we report a series of shape-memory polymers that enable unusual 'cold' programming and instantaneous shape recovery triggered by applying a contact pressure at ambient conditions. Moreover, the interdisciplinary integration of scientific principles drawn from two disparate fields--the fast-growing photonic crystal and shape-memory polymer technologies--enables fabrication of reconfigurable photonic crystals and simultaneously provides a simple and sensitive optical technique for investigating the intriguing shape-memory effects at nanoscale.

| S-EPMC4490579 | biostudies-literature

Photo-Responsive Shape-Memory and Shape-Changing Liquid-Crystal Polymer Networks.

Project description:"Surrounding matters" is a phrase that has become more significant in recent times when discussing polymeric materials. Although regular polymers do respond to external stimuli like softening of material at higher temperatures, that response is gradual and linear in nature. Smart polymers (SPs) or stimuli-responsive polymers (SRPs) behave differently to those external stimuli, as their behavior is more rapid and nonlinear in nature and even a small magnitude of external stimulus can cause noticeable changes in their shape, size, color or conductivity. Of these SRPs, two types of SPs with the ability to actively change can be differentiated: shape-memory polymers and shape-changing polymers. The uniqueness of these materials lies not only in the fast macroscopic changes occurring in their structure but also in that some of these shape changes are reversible. This paper presents a brief review of current progress in the area of light activated shape-memory polymers and shape-changing polymers and their possible field of applications.

| S-EPMC5452121 | biostudies-other

Shape Memory Polymer Foams with Tunable Degradation Profiles.

Project description:Uncontrolled hemorrhage is the leading cause of preventable death on the battlefield and results in ∼1.5 million deaths each year. The primary current treatment options are gauze and/or tourniquets, which are ineffective for up to 80% of wounds. Additionally, most hemostatic materials must be removed from the patient within <12 h, which limits their applicability in remote scenarios and can cause additional bleeding upon removal. Here, degradable shape memory polymer (SMP) foams were synthesized to overcome these limitations. SMP foams were modified with oxidatively labile ether groups and hydrolytically labile ester groups to degrade after implantation. Foam physical, thermal, and shape memory properties were assessed along with cytocompatibility and blood interactions. Degradation profiles were obtained in vitro in oxidative and hydrolytic media (3% H2O2 (oxidation) and 0.1 M NaOH (hydrolysis) at 37 °C). The resulting foams had tunable, clinically relevant degradation rates, with complete mass loss within 30-60 days. These SMP foams have potential to provide an easy-to-use, shape-filling hemostatic dressing that can be left in place during traumatic wound healing with future potential use in regenerative medicine applications.

| S-EPMC8456454 | biostudies-literature

New Approach to Shape Memory Polymer Composite Production Using Alkaline Lignin-Reinforced Epoxy-Based Shape Memory Polymers.

Project description:In the past few decades, there has been continued interest in shape memory polymers (SMPs), and tremendous efforts have been made to develop multifunctional composites of these SMPs to enhance the existing properties of SMPs. Although fossil-based sources are widely used in the production of shape memory polymer composites (SMPCs), the depletion of fossil-based resources and associated environmental problems increase interest toward renewable biobased products synthesized from natural resources. This study aims to produce alkaline lignin-reinforced SMPCs by using alkaline lignin in the SMP matrix. Thermo-mechanical, morphological, and shape memory tests are performed in order to reveal the effect of alkaline lignin usage in the SMP matrix on SMPC production. Differential scanning calorimetry analysis results show that adding alkaline lignin into the SMP matrix with 1 and 3% ratios led to an increase in T g values, while raising the alkaline lignin ratio to 5% decreased the T g value. According to the DMA results, increasing the alkaline lignin ratios caused an increase in the storage modulus of SMPCs, and the best storage modulus value was obtained at the 5% alkaline lignin ratio. The results of the three-point bending test also confirmed the results obtained from the DMA analysis, showing that an increasing alkaline lignin ratio caused an increase in the bending modulus. Scanning electron microscopy analysis showed a rough structure in 1 and 3% alkaline lignin supplementation, while a smoother structure was observed in 5% alkaline lignin supplementation. The smoother structure of the sample containing 5% alkaline lignin indicates that alkaline lignin supplementation exhibits a smoother surface by showing a plasticizing effect. As a result, it was observed that increasing the lignin ratio increased the polymer/alkaline lignin interaction, resulting in a harder structure and an increase in the flexural modulus value.

| S-EPMC10157668 | biostudies-literature

Biostable Shape Memory Polymer Foams for Smart Biomaterial Applications.

Project description:Polyurethane foams provide a wide range of applications as a biomaterial system due to the ability to tune their physical, chemical, and biological properties to meet the requirements of the intended applications. Another key parameter that determines the usability of this biomaterial is its degradability under body conditions. Several current approaches focus on slowing the degradation rate for applications that require the implant to be present for a longer time frame (over 100 days). Here, biostable shape memory polymer (SMP) foams were synthesized with added ether-containing monomers to tune the degradation rates. The physical, thermal and shape memory properties of these foams were characterized along with their cytocompatibility and blood interactions. Degradation profiles were assessed in vitro in oxidative (3% H2O2; real-time) and hydrolytic media (0.1 M NaOH; accelerated) at 37 °C. The resulting foams had tunable degradation rates, with up 15% mass remaining after 108 days, and controlled erosion profiles. These easy-to-use, shape-filling SMP foams have the potential for various biomaterial applications where longer-term stability without the need for implant removal is desired.

| S-EPMC8658902 | biostudies-literature

Thermoset Shape Memory Polymer Variable Stiffness 4D Robotic Catheters.

Project description:Variable stiffness catheters are typically composed of an encapsulated core. The core is usually composed of a low melting point alloy (LMPA) or a thermoplastic polymer (TP). In both cases, there is a need to encapsulate the core with an elastic material. This imposes a limit to the volume of variable stiffness (VS) material and limits miniaturization. This paper proposes a new approach that relies on the use of thermosetting materials. The variable stiffness catheter (VSC) proposed in this work eliminates the necessity for an encapsulation layer and is made of a unique biocompatible thermoset polymer with an embedded heating system. This significantly reduces the final diameter, improves manufacturability, and increases safety in the event of complications. The device can be scaled to sub-millimeter dimensions, while maintaining a high stiffness change. In addition, integration into a magnetic actuation system allows for precise actuation of one or multiple tools.

| S-EPMC8728812 | biostudies-literature

High Cycle-life Shape Memory Polymer at High Temperature.

Project description:High cycle-life is important for shape memory materials exposed to numerous cycles, and here we report shape memory polyimide that maintained both high shape fixity (Rf) and shape recovery (Rr) during the more than 1000 bending cycles tested. Its critical stress is 2.78 MPa at 250 °C, and the shape recovery process can produce stored energy of 0.218 J g(-1) at the efficiency of 31.3%. Its high Rf is determined by the large difference in storage modulus at rubbery and glassy states, while the high Rr mainly originates from its permanent phase composed of strong π-π interactions and massive chain entanglements. Both difference in storage modulus and overall permanent phase were preserved during the bending deformation cycles, and thus high Rf and Rr were observed in every cycle and the high cycle-life will expand application areas of SMPs enormously.

| S-EPMC5027533 | biostudies-literature

Virtual treatment of basilar aneurysms using shape memory polymer foam.

Project description:Numerical simulations are performed on patient-specific basilar aneurysms that are treated with shape memory polymer (SMP) foam. In order to assess the post-treatment hemodynamics, two modeling approaches are employed. In the first, the foam geometry is obtained from a micro-CT scan and the pulsatile blood flow within the foam is simulated for both Newtonian and non-Newtonian viscosity models. In the second, the foam is represented as a porous media continuum, which has permeability properties that are determined by computing the pressure gradient through the foam geometry over a range of flow speeds comparable to those of in vivo conditions. Virtual angiography and additional post-processing demonstrate that the SMP foam significantly reduces the blood flow speed within the treated aneurysms, while eliminating the high-frequency velocity fluctuations that are present within the pre-treatment aneurysms. An estimation of the initial locations of thrombus formation throughout the SMP foam is obtained by means of a low fidelity thrombosis model that is based upon the residence time and shear rate of blood. The Newtonian viscosity model and the porous media model capture similar qualitative trends, though both yield a smaller volume of thrombus within the SMP foam.

| S-EPMC3606648 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data