Ontology highlight
ABSTRACT:
SUBMITTER: Wu K
PROVIDER: S-EPMC5609847 | biostudies-literature | 2017 Aug
REPOSITORIES: biostudies-literature
Nature chemistry 20170306 8
The field of Ni-catalysed cross-coupling has seen rapid recent growth because of the low cost of Ni, its earth abundance, and its ability to promote unique cross-coupling reactions. Whereas advances in the related field of Pd-catalysed cross-coupling have been driven by ligand design, the development of ligands specifically for Ni has received minimal attention. Here, we disclose a class of phosphines that enable the Ni-catalysed Csp<sup>3</sup> Suzuki coupling of acetals with boronic acids to g ...[more]