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Equilibrium, Kinetic and Thermodynamic Study of Removal of Eosin Yellow from Aqueous Solution Using Teak Leaf Litter Powder.

ABSTRACT: Low-cost teak leaf litter powder (TLLP) was prepared as possible substitute for activated carbon. The feasibility of using the adsorbent to remove eosin yellow (EY) dye from aqueous solution was investigated through equilibrium adsorption, kinetic and thermodynamic studies. The removal of dye from aqueous solution was feasible but influenced by temperature, pH, adsorbent dosage and contact time. Variation in the initial concentration of dye did not influence the equilibrium contact time. Optimum adsorption of dye occurred at low adsorbent dosages, alkaline pH and high temperatures. Langmuir isotherm model best fit the equilibrium adsorption data and the maximum monolayer capacity of the adsorbent was 31.64?mg?g^-1 at 303?K. The adsorption process was best described by pseudo-second order kinetic model at 303?K. Boundary layer diffusion played a key role in the adsorption process. The mechanism of uptake of EY by TLLP was controlled by both liquid film diffusion and intraparticle diffusion. The values of mean adsorption free energy, E (7.91?kJ?mol^-1), and standard enthalpy, ?H° (+13.34?kJ?mol^-1), suggest physical adsorption. The adsorption process was endothermic and spontaneous. Teak leaf litter powder is a promising low-cost adsorbent for treating wastewaters containing eosin yellow.

SUBMITTER: Oyelude EO

PROVIDER: S-EPMC5610235 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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Equilibrium, Kinetic and Thermodynamic Study of Removal of Eosin Yellow from Aqueous Solution Using Teak Leaf Litter Powder.

Oyelude Emmanuel O EO Awudza Johannes A M JAM Twumasi Sylvester K SK

Scientific reports 20170922 1

Low-cost teak leaf litter powder (TLLP) was prepared as possible substitute for activated carbon. The feasibility of using the adsorbent to remove eosin yellow (EY) dye from aqueous solution was investigated through equilibrium adsorption, kinetic and thermodynamic studies. The removal of dye from aqueous solution was feasible but influenced by temperature, pH, adsorbent dosage and contact time. Variation in the initial concentration of dye did not influence the equilibrium contact time. Optimum ...[more]

PMID: 28939814

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Project description:Phenolic compound even at low concentrations, are considered to be priority pollutants due to their significant toxicity. Electrospinning was used to create a polyacrylonitril (PAN) nanofiber, which was then impregnated with graphene oxide (GO). After a preliminary investigation into the electrospinning parameters (e.g., using various voltages and polymer concentrations), the electrospun nanofibres were tuned, this study evaluated the effectiveness of these materials in removing phenolic compounds from wastewater through adsorption. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) were used to analyze the synthesized nanofiber mats. The scanning electron microscopy (SEM) analysis revealed that the structure of nanofiber mats was altered by the addition of graphene oxide (GO) in different ratios. Specifically, the surface of the fibres exhibited increased roughness, and the diameter of the fibres also experienced an increase. The average diameter of the fibres was measured to be (134.9 ± 21.43 nm) for the PAN/2.5% GO composite and (198 ± 33.94 nm) for the PAN/5% GO composite. FTIR spectra of the PAN/GO nanocomposites nanofiber displayed distinct peaks associated with graphene oxide (GO). These included a wide peak at 3400 cm-1, related to the presence of hydroxyl (O-H) groups, as well as peaks on 1600 as well as 1000 cm-1, which indicated the existence of epoxy groups. In this study response surface methodology (RSM) was implemented. To enhance the efficiency of removing substances, it is necessary to optimise parameters such as pH, contact time, and dosage of the adsorbent. The optimum pH for removing phenol via all nanofiber mats was determined to be 7, while at a dose of 2 mg dose adsorbents maximum removals for pure PAN, PAN/2.5 GO, and PAN/5 GO were 61.3941, 77.2118, and 92.76139%, respectively. All the adsorbents obey Langmuir isotherm model, and the empirical adsorption findings were fitted with the second-order model kinetically, also non-linear Elovich model. The maximal monolayer adsorption capacities for PAN, PAN/2.5 GO, and PAN/5 GO were found to be 57.4, 66.18, and 69.7 mg/g, respectively. Thermodynamic studies discovered that the adsorption of phenol on all adsorbents nanofiber mats was exothermic, the adsorption of phenol on nanofiber mats decreases as the temperature increases. All the adsorbents exhibit negative enthalpy and entropy. The PAN/GO composite's superior phenol removal suggested that it could be used as a latent adsorbent for efficient phenol removal from water and wastewater streams.

Dataset Information

Equilibrium, Kinetic and Thermodynamic Study of Removal of Eosin Yellow from Aqueous Solution Using Teak Leaf Litter Powder.

Publications

Equilibrium, Kinetic and Thermodynamic Study of Removal of Eosin Yellow from Aqueous Solution Using Teak Leaf Litter Powder.

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