A systematic study of the controlled generation of crystalline iron oxide nanoparticles on graphene using a chemical etching process.

ABSTRACT: Chemical vapor deposition (CVD) of carbon precursors employing a metal catalyst is a well-established method for synthesizing high-quality single-layer graphene. Yet the main challenge of the CVD process is the required transfer of a graphene layer from the substrate surface onto a chosen target substrate. This process is delicate and can severely degrade the quality of the transferred graphene. The protective polymer coatings typically used generate residues and contamination on the ultrathin graphene layer. In this work, we have developed a graphene transfer process which works without a coating and allows the transfer of graphene onto arbitrary substrates without the need for any additional post-processing. During the course of our transfer studies, we found that the etching process that is usually employed can lead to contamination of the graphene layer with the Faradaic etchant component FeCl₃, resulting in the deposition of iron oxide Fe _x O _y nanoparticles on the graphene surface. We systematically analyzed the removal of the copper substrate layer and verified that crystalline iron oxide nanoparticles could be generated in controllable density on the graphene surface when this process is optimized. It was further confirmed that the Fe _x O _y particles on graphene are active in the catalytic growth of carbon nanotubes when employing a water-assisted CVD process.

SUBMITTER: Krauß P 

PROVIDER: S-EPMC5629405 | biostudies-literature | 2017

REPOSITORIES: biostudies-literature