Ontology highlight
ABSTRACT:
SUBMITTER: Spezzati G
PROVIDER: S-EPMC5634748 | biostudies-literature | 2017 Oct
REPOSITORIES: biostudies-literature
Spezzati Giulia G Su Yaqiong Y Hofmann Jan P JP Benavidez Angelica D AD DeLaRiva Andrew T AT McCabe Jay J Datye Abhaya K AK Hensen Emiel J M EJM
ACS catalysis 20170907 10
Ceria-supported Pd is a promising heterogeneous catalyst for CO oxidation relevant to environmental cleanup reactions. Pd loaded onto a nanorod form of ceria exposing predominantly (111) facets is already active at 50 °C. Here we report a combination of CO-FTIR spectroscopy and theoretical calculations that allows assigning different forms of Pd on the CeO<sub>2</sub>(111) surface during reaction conditions. Single Pd atoms stabilized in the form of PdO and PdO<sub>2</sub> in a CO/O<sub>2</sub> ...[more]