Ontology highlight
ABSTRACT:
SUBMITTER: van de Watering FF
PROVIDER: S-EPMC5639366 | biostudies-literature | 2017 Sep
REPOSITORIES: biostudies-literature
van de Watering Fenna F FF van der Vlugt Jarl Ivar JI Dzik Wojciech I WI de Bruin Bas B Reek Joost N H JNH
Chemistry (Weinheim an der Bergstrasse, Germany) 20170830 52
The tripodal, tetradentate tris(1-(diphenylphosphanyl)-3-methyl-1H-indol-2-yl)phosphane PP<sub>3</sub> -ligand 1 stabilizes Ru in the Ru<sup>II</sup> , Ru<sup>I</sup> , and Ru<sup>0</sup> oxidation states. The octahedral [(PP<sub>3</sub> )Ru<sup>II</sup> (Cl)<sub>2</sub> ] (2), distorted trigonal bipyramidal [(PP<sub>3</sub> )Ru<sup>I</sup> (Cl)] (3), and trigonal bipyramidal [(PP<sub>3</sub> )Ru<sup>0</sup> (N<sub>2</sub> )] (4) complexes were isolated and characterized by single-crystal X-ray ...[more]