Classical strong metal-support interactions between gold nanoparticles and titanium dioxide.

ABSTRACT: Supported metal catalysts play a central role in the modern chemical industry but often exhibit poor on-stream stability. The strong metal-support interaction (SMSI) offers a route to control the structural properties of supported metals and, hence, their reactivity and stability. Conventional wisdom holds that supported Au cannot manifest a classical SMSI, which is characterized by reversible metal encapsulation by the support upon high-temperature redox treatments. We demonstrate a classical SMSI for Au/TiO₂, evidenced by suppression of CO adsorption, electron transfer from TiO₂ to Au nanoparticles, and gold encapsulation by a TiO _x overlayer following high-temperature reduction (reversed by subsequent oxidation), akin to that observed for titania-

SUBMITTER: Tang H 

PROVIDER: S-EPMC5640381 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature