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Synthesis of single-phase L10-FeNi magnet powder by nitrogen insertion and topotactic extraction.


ABSTRACT: Tetrataenite (L10-FeNi) is a promising candidate for use as a permanent magnet free of rare-earth elements because of its favorable properties. In this study, single-phase L10-FeNi powder with a high degree of order was synthesized through a new method, nitrogen insertion and topotactic extraction (NITE). In the method, FeNiN, which has the same ordered arrangement as L10-FeNi, is formed by nitriding A1-FeNi powder with ammonia gas. Subsequently, FeNiN is denitrided by topotactic reaction to derive single-phase L10-FeNi with an order parameter of 0.71. The transformation of disordered-phase FeNi into the L10 phase increased the coercive force from 14.5?kA/m to 142?kA/m. The proposed method not only significantly accelerates the development of magnets using L10-FeNi but also offers a new synthesis route to obtain ordered alloys in non-equilibrium states.

SUBMITTER: Goto S 

PROVIDER: S-EPMC5643398 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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Synthesis of single-phase L1<sub>0</sub>-FeNi magnet powder by nitrogen insertion and topotactic extraction.

Goto Sho S   Kura Hiroaki H   Watanabe Eiji E   Hayashi Yasushi Y   Yanagihara Hideto H   Shimada Yusuke Y   Mizuguchi Masaki M   Takanashi Koki K   Kita Eiji E  

Scientific reports 20171016 1


Tetrataenite (L1<sub>0</sub>-FeNi) is a promising candidate for use as a permanent magnet free of rare-earth elements because of its favorable properties. In this study, single-phase L1<sub>0</sub>-FeNi powder with a high degree of order was synthesized through a new method, nitrogen insertion and topotactic extraction (NITE). In the method, FeNiN, which has the same ordered arrangement as L1<sub>0</sub>-FeNi, is formed by nitriding A1-FeNi powder with ammonia gas. Subsequently, FeNiN is denitri  ...[more]

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