Ontology highlight
ABSTRACT:
SUBMITTER: Pitre SP
PROVIDER: S-EPMC5657382 | biostudies-literature | 2017 Apr
REPOSITORIES: biostudies-literature
Pitre Spencer P SP Yoon Tehshik P TP Scaiano Juan C JC
Chemical communications (Cambridge, England) 20170401 31
Titanium dioxide (TiO<sub>2</sub>) is a widely employed and inexpensive photocatalyst, but its use in organic synthesis has been limited by the short-wavelength ultraviolet irradiation typically used. We have discovered that TiO<sub>2</sub> particles efficiently mediate photocatalytic radical cation Diels-Alder cycloadditions using a simple visible light source, enabled by the formation of a visible light absorbing complex of the substrate on the semiconductor surface. ...[more]