Ontology highlight
ABSTRACT:
SUBMITTER: Crossley DL
PROVIDER: S-EPMC5666683 | biostudies-literature | 2015 Sep
REPOSITORIES: biostudies-literature
Crossley D L DL Cade I A IA Clark E R ER Escande A A Humphries M J MJ King S M SM Vitorica-Yrezabal I I Ingleson M J MJ Turner M L ML
Chemical science 20150612 9
Electrophilic borylation using BCl<sub>3</sub> and benzothiadiazole to direct the C-H functionalisation of an adjacent aromatic unit produces fused boracyclic materials with minimally changed HOMO energy levels but significantly reduced LUMO energy levels. <i>In situ</i> alkylation and arylation at boron using Al(alkyl)<sub>3</sub> or Zn(aryl)<sub>2</sub> is facile and affords boracycles that possess excellent stability towards protic solvents, including water, and display large bathochromic shi ...[more]