Ontology highlight
ABSTRACT:
SUBMITTER: Fieser ME
PROVIDER: S-EPMC5674182 | biostudies-literature | 2017 Nov
REPOSITORIES: biostudies-literature
Fieser Megan E ME Palumbo Chad T CT La Pierre Henry S HS Halter Dominik P DP Voora Vamsee K VK Ziller Joseph W JW Furche Filipp F Meyer Karsten K Evans William J WJ
Chemical science 20170907 11
A new series of Ln<sup>3+</sup> and Ln<sup>2+</sup> complexes has been synthesized using the tris(aryloxide)arene ligand system, ((<sup>Ad,Me</sup>ArO)<sub>3</sub>mes)<sup>3-</sup>, recently used to isolate a complex of U<sup>2+</sup>. The triphenol precursor, (<sup>Ad,Me</sup>ArOH)<sub>3</sub>mes, reacts with the Ln<sup>3+</sup> amides, Ln(NR<sub>2</sub>)<sub>3</sub> (R = SiMe<sub>3</sub>), to form a series of [((<sup>Ad,Me</sup>ArO)<sub>3</sub>mes)Ln] complexes, <b>1-Ln</b>. Crystallographic c ...[more]