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Crystal structure of bis[bis(4-azaniumylphenyl) sulfone] tetranitrate monohydrate.

ABSTRACT: In the title compound, the hydrated tetra-(nitrate) salt of dapsone (4,4'-di-amino-diphenyl-sulfone), 2C₁₂H₁₄N₂O₂S²⁺·4NO₃^-·H₂O {alternative name: bis[bis-(4,4'-di-aza-niumylphen-yl) sulfone] tetra-nitrate monohydrate}, the cations are conformationally similar, with comparable dihedral angles between the two benzene rings in each of 70.03?(18) and 69.69?(19)°. In the crystal, mixed cation-anion-water mol-ecule layers lying parallel to the (001) plane are formed through N-H?O, O-H?O and C-H?O hydrogen-bonding inter-actions and these layers are further extended into an overall three-dimensional supra-molecular network structure. Inter-ring ?-? inter-actions are also present [minimum ring centroid separation = 3.693?(3)?Å].

SUBMITTER: Benahsene AH

PROVIDER: S-EPMC5683499 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of bis[bis(4-azaniumylphenyl) sulfone] tetranitrate monohydrate.

Benahsene Amani Hind AH Bendjeddou Lamia L Merazig Hocine H

Acta crystallographica. Section E, Crystallographic communications 20171020 Pt 11

In the title compound, the hydrated tetra-(nitrate) salt of dapsone (4,4'-di-amino-diphenyl-sulfone), 2C12H14N2O2S2+·4NO3-·H2O {alternative name: bis[bis-(4,4'-di-aza-niumylphen-yl) sulfone] tetra-nitrate monohydrate}, the cations are conformationally similar, with comparable dihedral angles between the two benzene rings in each of 70.03 (18) and 69.69 (19)°. In the crystal, mixed cation-anion-water mol-ecule ...[more]

PMID: 29152359

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