Ontology highlight
ABSTRACT:
SUBMITTER: Sano Y
PROVIDER: S-EPMC5696092 | biostudies-literature | 2017 Nov
REPOSITORIES: biostudies-literature
Sano Yohei Y Lau Nathanael N Weitz Andrew C AC Ziller Joseph W JW Hendrich Michael P MP Borovik A S AS
Inorganic chemistry 20171107 22
Bimetallic complexes are important sites in metalloproteins but are often difficult to prepare synthetically. We have previously introduced an approach to form discrete bimetallic complexes with M<sup>II</sup>-(μ-OH)-Fe<sup>III</sup> (M<sup>II</sup> = Mn, Fe) cores using the tripodal ligand N,N',N″-[2,2',2″-nitrilotris(ethane-2,1-diyl)]tris(2,4,6-trimethylbenzenesulfonamido) ([MST]<sup>3-</sup>). This series is extended to include the rest of the late 3d transition metal ions (M<sup>II</sup> = C ...[more]