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Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts.


ABSTRACT: The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.

SUBMITTER: Zhang W 

PROVIDER: S-EPMC5698721 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts.

Zhang Wuyuan W   Gacs Jenő J   Arends Isabel W C E IWCE   Hollmann Frank F  

ChemCatChem 20170907 20


The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions. ...[more]

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