Ontology highlight
ABSTRACT:
SUBMITTER: Obligacion JV
PROVIDER: S-EPMC5701518 | biostudies-literature | 2017 Feb
REPOSITORIES: biostudies-literature
Obligacion Jennifer V JV Bezdek Máté J MJ Chirik Paul J PJ
Journal of the American Chemical Society 20170210 7
Cobalt catalysts with electronically enhanced site selectivity have been developed, as evidenced by the high ortho-to-fluorine selectivity observed in the C(sp<sup>2</sup>)-H borylation of fluorinated arenes. Both the air-sensitive cobalt(III) dihydride boryl 4-Me-(<sup>iPr</sup>PNP)Co(H)<sub>2</sub>BPin (1) and the air-stable cobalt(II) bis(pivalate) 4-Me-(<sup>iPr</sup>PNP)Co(O<sub>2</sub>C<sup>t</sup>Bu)<sub>2</sub> (2) compounds were effective and exhibited broad functional group tolerance a ...[more]