Diverse modes of reactivity of 6-(chloromethyl)-6-methylfulvene.
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ABSTRACT:
SUBMITTER: Erden I
PROVIDER: S-EPMC5708559 | biostudies-literature | 2017 May
REPOSITORIES: biostudies-literature
Publications
Diverse modes of reactivity of 6-(chloromethyl)-6-methylfulvene.
Erden Ihsan I Gronert Scott S Cabrera Gabriel G Coskun Necdet N Tapken Marco M
European journal of organic chemistry 20170501 20
The title compound exhibits a number of reactivities toward nucleophiles/bases owing to the presence of several electrophilic and potentially nucleophilic sites in the molecule. We explored the reactions of 6-(chloromethyl)-6-methylfulvene with oxygen- and nitrogen nucleophiles and bases as well as a carbon-based nucleophile (an enamine) and realized all possible reactivity modes predicted on the basis of electrophilic and nucleophilic positions in this compound. ...[more]
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