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Plasma-Assisted Synthesis of Monodispersed and Robust Ruthenium Ultrafine Nanocatalysts for Organosilane Oxidation and Oxygen Evolution Reactions.


ABSTRACT: We report a facile and general approach for preparing ultrafine ruthenium nanocatalysts by using a plasma-assisted synthesis at <100?°C. The resulting Ru nanoparticles are monodispersed (typical size 2?nm) and remain that way upon loading onto carbon and TiO2 supports. This gives robust catalysts with excellent activities in both organosilane oxidation and the oxygen evolution reaction.

SUBMITTER: Gnanakumar ES 

PROVIDER: S-EPMC5725707 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Plasma-Assisted Synthesis of Monodispersed and Robust Ruthenium Ultrafine Nanocatalysts for Organosilane Oxidation and Oxygen Evolution Reactions.

Gnanakumar Edwin S ES   Ng Wesley W   Coşkuner Filiz Bilge B   Rothenberg Gadi G   Wang Sheng S   Xu Hualong H   Pastor-Pérez Laura L   Pastor-Blas M Mercedes MM   Sepúlveda-Escribano Antonio A   Yan Ning N   Shiju N Raveendran NR  

ChemCatChem 20171012 22


We report a facile and general approach for preparing ultrafine ruthenium nanocatalysts by using a plasma-assisted synthesis at <100 °C. The resulting Ru nanoparticles are monodispersed (typical size 2 nm) and remain that way upon loading onto carbon and TiO<sub>2</sub> supports. This gives robust catalysts with excellent activities in both organosilane oxidation and the oxygen evolution reaction. ...[more]

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