Dataset Information
Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments.
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ABSTRACT:
SUBMITTER: Braunschweig H
PROVIDER: S-EPMC5729409 | biostudies-literature | 2015 May
REPOSITORIES: biostudies-literature
Publications
Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments.
Chemical science 20150310 5
The M-(η<sup>2</sup>-BMn) complex [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(OC)<sub>2</sub>Mn{μ-B(Cl)(<i>t</i>Bu)Au(PPh<sub>3</sub>)}] (<b>2</b>) can be functionalized <i>via</i> halide substitution reactions to afford isostructural complexes [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(OC)<sub>2</sub>Mn{μ-B(R)(<i>t</i>Bu)Au(PPh<sub>3</sub>)}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh<sub>3</sub>)] (M = Au, Ag and Cu) in the presence of halide abstraction reag ...[more]