Ontology highlight
ABSTRACT:
SUBMITTER: Roizen JL
PROVIDER: S-EPMC5732049 | biostudies-literature | 2017 Dec
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20171121 24
Recently, we reported a convergent cyclopropanation-Cope approach to the core of ineleganolide, which was the first disclosed synthesis of the core of the norditerpene natural product ineleganolide. In this complementary work, a model system for the core of ineleganolide has been prepared through a series of tandem cyclopropanation-Cope and translactonization-Cope rearrangements. Work with this model system has enriched our understanding of the cyclopropanation-Cope rearrangement sequence. Addit ...[more]