Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex.
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ABSTRACT:
SUBMITTER: McCarthy BD
PROVIDER: S-EPMC5761499 | biostudies-literature | 2015 May
REPOSITORIES: biostudies-literature
Publications
Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex.
McCarthy Brian D BD Donley Carrie L CL Dempsey Jillian L JL
Chemical science 20150305 5
A Ni(ii) bisphosphine dithiolate compound degrades into an electrode-adsorbed film that can evolve hydrogen under reducing and protic conditions. An electrochemical study suggests that the degradation mechanism involves an initial concerted proton-electron transfer. The potential susceptibility of Ni-S bonds in molecular hydrogen evolution catalysts to degradation <i>via</i> C-S bond cleavage is discussed. ...[more]
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