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Crystal structure of the ?4-ketimine titanium complex (di-phenyl-amido-?N){3-methyl-6-[(4-methyl-phen-yl)(phenyl-aza-nid-yl)methyl-idene]cyclo-hexa-2,4-dien-1-yl-?2N,C1}(?5-penta-methyl-cyclo-penta-dien-yl)titanium(IV).
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ABSTRACT:
SUBMITTER: Fischer M
PROVIDER: S-EPMC5778480 | biostudies-literature | 2018 Jan
REPOSITORIES: biostudies-literature
Publications
Crystal structure of the η<sup>4</sup>-ketimine titanium complex (di-phenyl-amido-κ<i>N</i>){3-methyl-6-[(4-methyl-phen-yl)(phenyl-aza-nid-yl)methyl-idene]cyclo-hexa-2,4-dien-1-yl-κ<sup>2</sup><i>N</i>,<i>C</i><sup>1</sup>}(η<sup>5</sup>-penta-methyl-cyclo-penta-dien-yl)titanium(IV).
Acta crystallographica. Section E, Crystallographic communications 20180101 Pt 1
The mol-ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η<sup>5</sup>-C<sub>10</sub>H<sub>15</sub>)(η<sup>4</sup>-C<sub>21</sub>H<sub>19</sub>N)(C<sub>12</sub>H<sub>10</sub>N)], shows a three-legged piano-stool geometry at the central Ti<sup>IV</sup> atom, comprising of one penta-methyl-cyclo-penta-dienyl ligand, one bidentate ketimine ligand in an η<sup>4</sup>-coordination mode and one monodentate di-phenyl-amide ligand. Except for van der Waals forces, there are no signi ...[more]