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Crystal structure of the ?4-ketimine titanium complex (di-phenyl-amido-?N){3-methyl-6-[(4-methyl-phen-yl)(phenyl-aza-nid-yl)methyl-idene]cyclo-hexa-2,4-dien-1-yl-?2N,C1}(?5-penta-methyl-cyclo-penta-dien-yl)titanium(IV).

ABSTRACT: The mol-ecular structure of the title titanium(IV) half-sandwich complex, [Ti(?5-C10H15)(?4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one penta-methyl-cyclo-penta-dienyl ligand, one bidentate ketimine ligand in an ?4-coordination mode and one monodentate di-phenyl-amide ligand. Except for van der Waals forces, there are no significant inter-molecular inter-actions in the crystal.

SUBMITTER: Fischer M

PROVIDER: S-EPMC5778480 | biostudies-literature | 2018 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of the η4-ketimine titanium complex (di-phenyl-amido-κN){3-methyl-6-[(4-methyl-phen-yl)(phenyl-aza-nid-yl)methyl-idene]cyclo-hexa-2,4-dien-1-yl-κ2N,C1}(η5-penta-methyl-cyclo-penta-dien-yl)titanium(IV).

Fischer Malte M Schmidtmann Marc M Beckhaus Rüdiger R

Acta crystallographica. Section E, Crystallographic communications 20180101 Pt 1

The mol-ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one penta-methyl-cyclo-penta-dienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate di-phenyl-amide ligand. Except for van der Waals forces, there are no signi ...[more]

PMID: 29416886

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