Ontology highlight
ABSTRACT:
SUBMITTER: Kurouchi H
PROVIDER: S-EPMC5785089 | biostudies-literature | 2018 Feb
REPOSITORIES: biostudies-literature
Kurouchi Hiroaki H Singleton Daniel A DA
Nature chemistry 20180101 2
Any long-lived chemical structure in solution is subject to statistical energy equilibration, so the history of any specific structure does not affect its subsequent reactions. This is not true for very short-lived intermediates because energy equilibration takes time. Here, this idea is applied to achieve the 'energy labelling' of a reactive intermediate. The selectivity of the ring-opening α-cleavage reaction of the 1-methylcyclobutoxy radical is found here to vary broadly depending on how the ...[more]