Ontology highlight
ABSTRACT:
SUBMITTER: Zhao XQ
PROVIDER: S-EPMC5795553 | biostudies-literature | 2018 Feb
REPOSITORIES: biostudies-literature
Zhao Xiao-Qing XQ Xiang Shuo S Wang Jin J Bao Dong-Xu DX Li Yun-Chun YC
ChemistryOpen 20180202 2
Two 3<i>d</i>-4<i>f</i> hetero-metal pentanuclear complexes with the formula {[Cr<sup>III</sup><sub>2</sub>Ln<sup>III</sup><sub>3</sub>L<sub>10</sub>(OH)<sub>6</sub>(H<sub>2</sub>O)<sub>2</sub>]Et<sub>3</sub>NH} [Ln=Tb (<b>1</b>), Dy (<b>2</b>); HL=pivalic acid, Et<sub>3</sub>N=triethylamine] have been produced. The metal core of each cluster is made up of a trigonal bipyramid with three Ln<sup>III</sup> ions (plane) and two Cr<sup>III</sup> ions (above and below) held together by six <i>μ</i><s ...[more]