Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes.

ABSTRACT: Mesoporous nitrogen-doped silicon carbide catalysts with integrated cobalt nanoparticles (Co@N-SiC) were synthesized by the thermal decomposition of a microphase-separated block copolymer of polycarbosilane and polyethylene. The catalysts are highly active, reusable and offer selective hydrogenation of the nitro group in the presence of hydrogenation-sensitive functional groups.

SUBMITTER: Eckardt M

PROVIDER: S-EPMC5803264 | biostudies-literature | 2018 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Nitrogen-doped mesoporous SiC materials with catalytically active cobalt nanoparticles for the efficient and selective hydrogenation of nitroarenes.

Eckardt Mirco M Zaheer Muhammad M Kempe Rhett R

Scientific reports 20180207 1

Mesoporous nitrogen-doped silicon carbide catalysts with integrated cobalt nanoparticles (Co@N-SiC) were synthesized by the thermal decomposition of a microphase-separated block copolymer of polycarbosilane and polyethylene. The catalysts are highly active, reusable and offer selective hydrogenation of the nitro group in the presence of hydrogenation-sensitive functional groups. ...[more]

PMID: 29416097

Similar Datasets

Palladium nanoparticles on chitin-derived nitrogen-doped carbon materials for carbon dioxide hydrogenation into formic acid.

Project description:Utilizing waste carbon resources to produce chemicals and materials is beneficial to mitigate the fossil fuel consumption and the global warming. In this study, ocean-based chitin biomass and waste shrimp shell powders were employed as the feedstock to prepare Pd loaded nitrogen-doped carbon materials as the catalysts for carbon dioxide (CO2)/bicarbonate hydrogenation into formic acid, which simultaneously converts waste biomass into useful materials and CO2 into a valuable chemical. Three different preparation methods were examined, and the two-stage calcination was the most efficient one to obtain N-doped carbon material with good physicochemical properties as the best Pd support. The highest formic acid yield was achieved of ∼77% at 100 °C in water with KHCO3 substrate under optimal condition with a TON of 610. The nitrogen content and N functionalities of the as-synthesized carbon materials were crucial which could serve as anchor sites for the Pd precursor and assist the formation of well-dispersed and small-sized Pd NPs for boosted catalytic activity. The study puts forward a facile, inexpensive and environmentally benign way for simultaneous valorization of oceanic waste biomass and carbon dioxide into valuable products.

| S-EPMC9693910 | biostudies-literature

Highly-efficient RuNi single-atom alloy catalysts toward chemoselective hydrogenation of nitroarenes.

Project description:The design and exploitation of high-performance catalysts have gained considerable attention in selective hydrogenation reactions, but remain a huge challenge. Herein, we report a RuNi single atom alloy (SAA) in which Ru single atoms are anchored onto Ni nanoparticle surface via Ru-Ni coordination accompanied with electron transfer from sub-surface Ni to Ru. The optimal catalyst 0.4% RuNi SAA exhibits simultaneously improved activity (TOF value: 4293 h-1) and chemoselectivity toward selective hydrogenation of 4-nitrostyrene to 4-aminostyrene (yield: >99%), which is, to the best of our knowledge, the highest level compared with reported heterogeneous catalysts. In situ experiments and theoretical calculations reveal that the Ru-Ni interfacial sites as intrinsic active centers facilitate the preferential cleavage of N-O bond with a decreased energy barrier by 0.28 eV. In addition, the Ru-Ni synergistic catalysis promotes the formation of intermediates (C8H7NO* and C8H7NOH*) and accelerates the rate-determining step (hydrogenation of C8H7NOH*).

| S-EPMC9178046 | biostudies-literature

PAF-derived nitrogen-doped 3D Carbon Materials for Efficient Energy Conversion and Storage.

Project description:Owing to the shortage of the traditional fossil fuels caused by fast consumption, it is an urgent task to develop the renewable and clean energy sources. Thus, advanced technologies for both energy conversion (e.g., solar cells and fuel cells) and storage (e.g., supercapacitors and batteries) are being studied extensively. In this work, we use porous aromatic framework (PAF) as precursor to produce nitrogen-doped 3D carbon materials, i.e., N-PAF-Carbon, by exposing NH3 media. The "graphitic" and "pyridinic" N species, large surface area, and similar pore size as electrolyte ions endow the nitrogen-doped PAF-Carbon with outstanding electronic performance. Our results suggest the N-doping enhance not only the ORR electronic catalysis but also the supercapacitive performance. Actually, the N-PAF-Carbon obtains ~70?mV half-wave potential enhancement and 80% increase as to the limiting current after N doping. Moreover, the N-PAF-Carbon displays free from the CO and methanol crossover effect and better long-term durability compared with the commercial Pt/C benchmark. Moreover, N-PAF-Carbon also possesses large capacitance (385?F g(-1)) and excellent performance stability without any loss in capacitance after 9000 charge-discharge cycles. These results clearly suggest that PAF-derived N-doped carbon material is promising metal-free ORR catalyst for fuel cells and capacitor electrode materials.

| S-EPMC4456730 | biostudies-literature

Facile Preparation of Cobalt Nanoparticles Encapsulated Nitrogen-Doped Carbon Sponge for Efficient Oxygen Reduction Reaction.

Project description:The facile preparation of non-noble metal nanoparticle loaded carbon nanomaterials is promising for efficient oxygen reduction reaction (ORR) electrocatalysis. Herein, a facile preparation strategy is proposed to prepare nitrogen-doped carbon sponge loaded with fine cobalt nanoparticles by the direct pyrolysis of the cobalt ions adsorbed polymeric precursor. The polymeric sponge precursor with continuous framework and high porosity is formed by the self-assembly of a poly(amic acid). Taking advantage of the negatively charged surface and porous structure, cobalt ions can be efficiently adsorbed into the polymeric sponge. After pyrolysis, fine cobalt nanoparticles covered by carbon layers are formed, while the sponge-like structure of the precursor is also well-preserved in order to give cobalt nanoparticles loaded nitrogen-doped carbon sponges (Co/CoO@NCS) with a high loading content of 44%. The Co/CoO@NCS exhibits promising catalytic activity toward ORR with a half-wave potential of 0.830 V and a limiting current density of 4.71 mA cm-2. Overall, we propose a facile polymer self-assembly strategy to encapsulate transition metal nanoparticles with high loading content on a nitrogen-doped carbon sponge for efficient ORR catalysis.

| S-EPMC9920104 | biostudies-literature

Selective and Additive-Free Hydrogenation of Nitroarenes Mediated by a DMSO-Tagged Molecular Cobalt Corrole Catalyst.

Project description:We report on the first cobalt corrole that effectively mediates the homogeneous hydrogenation of structurally diverse nitroarenes to afford the corresponding amines. The given catalyst is easily assembled prior to use from 4-tert-butylbenzaldehyde and pyrrole followed by metalation of the resulting corrole macrocycle with cobalt(II) acetate. The thus-prepared complex is self-contained in that the hydrogenation protocol is free from the requirement for adding any auxiliary reagent to elicit the catalytic activity of the applied metal complex. Moreover, a containment system is not required for the assembly of the hydrogenation reaction set-up as both the autoclave and the reaction vessels are readily charged under a regular laboratory atmosphere.

| S-EPMC8252576 | biostudies-literature

An efficient Terahertz rectifier on the graphene/SiC materials platform.

Project description:We present an efficient Schottky-diode detection scheme for Terahertz (THz) radiation, implemented on the material system epitaxial graphene on silicon carbide (SiC). It employs SiC as semiconductor and graphene as metal, with an epitaxially defined interface. For first prototypes, we report on broadband operation up to 580 GHz, limited only by the RC circuitry, with a responsivity of 1.1 A/W. Remarkably, the voltage dependence of the THz responsivity displays no deviations from DC responsivity, which encourages using this transparent device for exploring the high frequency limits of Schottky rectification in the optical regime. The performance of the detector is demonstrated by resolving sharp spectroscopic features of ethanol and acetone in a THz transmission experiment.

| S-EPMC6671971 | biostudies-literature

Ultrafine Pd Nanoparticles Anchored on Nitrogen-Doping Carbon for Boosting Catalytic Transfer Hydrogenation of Nitroarenes.

Project description:The catalytic performance of metal particles is closely related to the particle size. In this article, ultrafine palladium nanoparticles anchored on nitrogen-doping carbon support (Pd/N-XC72R) were fabricated, wherein the N-XC72R was prepared through low-temperature annealing of Vulcan XC72R carbon with urea at 300 °C. Nitrogen dopant on the surface of carbon support can remarkably strengthen the affinity of the metal nanoparticles onto the support. Compared with the Vulcan XC-72R-supported Pd catalyst, the prepared Pd/N-XC72R delivered superior catalytic activity for the transfer hydrogenation of nitroarenes with formic acid as the hydrogen donor at ambient temperature. Our strategy may provide an effective and feasible approach to fabricate N-functionalized carbon materials and construct high-performance ultrasmall metal nanoparticle heterogeneous catalysts.

| S-EPMC6645512 | biostudies-literature

Novel sol-gel precursors for thin mesoporous eu(3+)-doped silica coatings as efficient luminescent materials.

Project description:Europium(III) ions containing mesoporous silica coatings have been prepared via a solvent evaporation-induced self-assembly (EISA) approach of different single-source precursors (SSPs) in the presence of Pluronic P123 as a structure-directing agent, using the spin-coating process. A deliberate tailoring of the chemical composition of the porous coatings with various Si:Eu ratios was achieved by processing mixtures of tetraethylorthosilicate (TEOS) and Eu(3+)-coordinated SSPs. Small-angle X-ray scattering (SAXS) and transmission electron microscopy (TEM) analyses demonstrate that the thin metal oxide-doped silica coatings consist of a porous network with a short-range order of the pore structure, even at high europium(III) loadings. Furthermore, luminescence properties were investigated at different temperatures and different degrees of Eu(3+) contents. The photoluminescence spectra clearly show characteristic emission peaks corresponding to the (5)D0 → (7)FJ (J = 0-5) transitions resulting in a red luminescence visible by the eyes, although the films have a very low thickness (150-200 nm).

| S-EPMC3597185 | biostudies-other

Micelle-template synthesis of nitrogen-doped mesoporous graphene as an efficient metal-free electrocatalyst for hydrogen production.

Project description:Synthesis of mesoporous graphene materials by soft-template methods remains a great challenge, owing to the poor self-assembly capability of precursors and the severe agglomeration of graphene nanosheets. Herein, a micelle-template strategy to prepare porous graphene materials with controllable mesopores, high specific surface areas and large pore volumes is reported. By fine-tuning the synthesis parameters, the pore sizes of mesoporous graphene can be rationally controlled. Nitrogen heteroatom doping is found to remarkably render electrocatalytic properties towards hydrogen evolution reactions as a highly efficient metal-free catalyst. The synthesis strategy and the demonstration of highly efficient catalytic effect provide benchmarks for preparing well-defined mesoporous graphene materials for energy production applications.

| S-EPMC4271267 | biostudies-literature

Atomic cobalt on nitrogen-doped graphene for hydrogen generation.

Project description:Reduction of water to hydrogen through electrocatalysis holds great promise for clean energy, but its large-scale application relies on the development of inexpensive and efficient catalysts to replace precious platinum catalysts. Here we report an electrocatalyst for hydrogen generation based on very small amounts of cobalt dispersed as individual atoms on nitrogen-doped graphene. This catalyst is robust and highly active in aqueous media with very low overpotentials (30 mV). A variety of analytical techniques and electrochemical measurements suggest that the catalytically active sites are associated with the metal centres coordinated to nitrogen. This unusual atomic constitution of supported metals is suggestive of a new approach to preparing extremely efficient single-atom catalysts.

| S-EPMC4639894 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data