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Restructuring and Hydrogen Evolution on Pt Nanoparticle.

ABSTRACT: The restructuring of nanoparticles at the in situ condition is a common but complex phenomenon in nanoscience. Here, we present the first systematic survey on the structure dynamics and its catalytic consequence for hydrogen evolution reaction (HER) on Pt nanoparticles, as represented by a magic number Pt44 octahedron (?1 nm size). Using a first principles calculation based global structure search method, we stepwise follow the significant nanoparticle restructuring under HER conditions as driven by thermodynamics to expose {100} facets, and reveal the consequent large activity enhancement due to the marked increase of the concentration of the active site, being identified to be apex atoms. The enhanced kinetics is thus a "byproduct" of the thermodynamical restructuring. Based on the results, the best Pt catalyst for HER is predicted to be ultrasmall Pt particles without core atoms, a size below ?20 atoms.

SUBMITTER: Wei GF

PROVIDER: S-EPMC5811100 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Restructuring and Hydrogen Evolution on Pt Nanoparticle.

Wei Guang-Feng GF Liu Zhi-Pan ZP

Chemical science 20141126 2

The restructuring of nanoparticles at the in situ condition is a common but complex phenomenon in nanoscience. Here, we present the first systematic survey on the structure dynamics and its catalytic consequence for hydrogen evolution reaction (HER) on Pt nanoparticles, as represented by a magic number Pt44 octahedron (∼1 nm size). Using a first principles calculation based global structure search method, we stepwise follow the significant nanoparticle restructuring under HER c ...[more]

PMID: 29560237

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